JamieGator32 That KB is only applicable to vCenter Server 5.1/5.5.
netwatcher_s1 Here is a great blog that illustrates what you need to do: http://blogs.vmware.com/vsphere/2015/10/reconfiguring-and-repointing-deployment-models-in-vcenter-server-6-0-update-1.html
It sounds like you didn't quite get the entire process completed. Also note, you need to be running at least vCenter 6.0 Update 1 in order to perform this repoint operation.
And to clarify your vCenter Database does not live on the PSC. It still lives on the vCenter Server. To learn more about the PSC you should take a look at this article: http://kb.vmware.com/selfservice/microsites/search.do?language=en_US&cmd=displayKC&externalId=2113115
If you have other questions that aren't answered by the 2 articles just let me know.